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In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

《能源前沿（英文）》 2023年 第17卷 第5期   页码 654-663 doi: 10.1007/s11708-023-0885-5

摘要： Transition metal sulfides are commonly studied as photocatalysts for water splitting in solar-to-fuel conversion. However, the effectiveness of these photocatalysts is limited by the recombination and restricted light absorption capacity of carriers. In this paper, a broad spectrum responsive In2S3/Bi2S3 heterojunction is constructed by in-situ integrating Bi2S3 with the In2S3, derived from an In-MOF precursor, via the high-temperature sulfidation and solvothermal methods. Benefiting from the synergistic effect of wide-spectrum response, effective charge separation and transfer, and strong heterogeneous interfacial contacts, the In2S3/Bi2S3 heterojunction demonstrates a rate of 0.71 mmol/(g∙h), which is 2.2 and 1.7 times as much as those of In2S3 (0.32 mmol/(g∙h) and Bi2S3 (0.41 mmol/(g∙h)), respectively. This paper provides a novel idea for rationally designing innovative heterojunction photocatalysts of transition metal sulfides for photocatalytic hydrogen production.

关键词： photocatalytic hydrogen production     wide-spectrum response     metal sulfides     MOFs derivative     heterogeneous interfacial contact    

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NO<sub>xsub> and H<sub>2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

《能源前沿（英文）》 2021年 第15卷 第1期   页码 4-13 doi: 10.1007/s11708-020-0804-y

摘要： Low NO combustion of blended coals is widely used in coal-fired boilers in China to control NO emission; thus, it is necessary to understand the formation mechanism of NO and H S during the combustion of blended coals. This paper focused on the investigation of reductive gases in the formation of NO and H S in the reductive zone of blended coals during combustion. Experiments with Zhundong (ZD) and Commercial (GE) coal and their blends with different mixing ratios were conducted in a drop tube furnace at 1200°C–1400°C with an excessive air ratio of 0.6–1.2. The coal conversion and formation characteristics of CO, H S, and NO in the fuel-rich zone were carefully studied under different experimental conditions for different blend ratios. Blending ZD into GE was found to increase not only the coal conversion but also the concentrations of CO and H S as NO reduction accelerated. Both the CO and H S concentrations inblended coal combustion increase with an increase in the combustion temperature and a decrease in the excessive air ratio. Based on accumulated experimental data, one interesting finding was that NO and H S from blended coal combustion were almost directly dependent on the CO concentration, and the CO concentration of the blended coal combustion depended on the single char gasification conversion.Thus, CO, NO , and H S formation characteristics from blended coal combustion can be well predicted by single char gasification kinetics.

关键词： blended coal combustion     NOx formation     H2S formation     air staged combustion    

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Photoelectrocatalytic generation of H and S from toxic HS by using a novel BiOI/WO nanoflake array photoanode

《能源前沿（英文）》 2021年 第15卷 第3期   页码 744-751 doi: 10.1007/s11708-021-0775-7

摘要： In this paper, a photoelectrocatalytic (PEC) recovery of toxic H2S into H2 and S system was proposed using a novel bismuth oxyiodide (BiOI)/ tungsten trioxide (WO3) nano-flake arrays (NFA) photoanode. The BiOI/WO3 NFA with a vertically aligned nanostructure were uniformly prepared on the conductive substrate via transformation of tungstate following an impregnating hydroxylation of BiI3. Compared to pure WO3 NFA, the BiOI/WO3 NFA promotes a significant increase of photocurrent by 200%. Owing to the excellent stability and photoactivity of the BiOI/WO3 NFA photoanode and I–/I 3− catalytic system, the PEC system toward splitting of H2S totally converted S2– into S without any polysulfide ( Sx n−) under solar-light irradiation. Moreover, H2 was simultaneously generated at a rate of about 0.867 mL/(h·cm). The proposed PEC H2S splitting system provides an efficient and sustainable route to recover H2 and S.

关键词： bismuth oxyiodide (BiOI)/ tungsten trioxide (WO3) nano-flake arrays (NFA)     photoelectrocatalytic (PEC)     H2S splitting     H2     S    

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催化氧化净化黄磷尾气中的磷和硫

宁平,Hans-JörgBart,王学谦,马丽萍,陈梁

《中国工程科学》 2005年 第7卷 第6期   页码 27-35

摘要： 研究了用普通活性炭和自制催化剂KU2催化氧化净化黄磷尾气的方法；讨论了固定床系统中常压下、温度20～140℃，催化剂上磷和硫化氢的吸附特征。KU2和活性炭都能通过催化氧化过程有效脱除黄磷尾气中的P<sub>4sub>，PH<sub>3sub>和H<sub>2sub>S杂质，随着反应温度和氧含量增加可显著提高净化效果，在最优条件下

关键词： 催化剂     催化氧化     H<sub>2sub>S     P<sub>4sub>     PH<sub>3sub>     固定床    

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Sulfur-deficient CoNi<sub>2sub>S<sub>4sub> nanoparticles-anchored porous carbon nanofibers as bifunctional

《化学科学与工程前沿（英文）》 2023年 第17卷 第11期   页码 1707-1717 doi: 10.1007/s11705-023-2308-x

摘要： Water electrolysis technology is considered to be one of the most promising means to produce hydrogen. Herein, aiming at the problems of high overpotential and slow kinetics in water splitting, N-doped porous carbon nanofibers-coupled CoNi2S4 nanoparticles are prepared as bifunctional electrocatalyst. In the strategy, NaCl is used as the template to prepare porous carbon nanofibers with a large surface area, and sulfur vacancies are created to modulate the electronic structure of CoNi2S4. Electron spin resonance confirms the formation of abundant sulfur vacancies, which largely reduce the bandgap of CoNi2S4 from 1.68 to 0.52 eV. The narrowed bandgap is conducive to the migration of valence electrons and decreases the charge transfer resistance for electrocatalytic reaction. Moreover, the uniform distribution of CoNi2S4 nanoparticles on carbon nanofibers can prevent the aggregation and facilitate the exposure of electrochemical active sites. Therefore, the composite catalyst exhibits low overpotentials of 340 mV@100 mA·cm–2 for oxygen evolution reaction and 380 mV@100 mA·cm–2 for hydrogen evolution reaction. The assembled electrolyzer requires 1.64 V to achieve 10 mA·cm–2 for overall water-splitting with good long-term stability. The excellent performance results from the synergistic effect of porous structures, sulfur deficiency, nitrogen doping, and the well-dispersed active component.

关键词： nanoparticle     sulfur vacancy     porous carbon nanofiber     transition metal sulfides     electrolysis    

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China’s pre-2020 CO

Hailin WANG

《能源前沿（英文）》 2019年 第13卷 第3期   页码 571-578 doi: 10.1007/s11708-019-0640-0

摘要： China achieved the reduction of CO intensity of GDP by 45% compared with 2005 at the end of 2017, realizing the commitment at 2009 Copenhagen Conference on emissions reduction 3 years ahead of time. In future implementation of the “13th Five-Year Plan (FYP),” with the decline of economic growth rate, decrease of energy consumption elasticity and optimization of energy structure, the CO intensity of GDP will still have the potential for decreasing before 2020. By applying KAYA Formula decomposition, this paper makes the historical statistics of the GDP energy intensity decrease and CO intensity of energy consumption since 2005, and simulates the decrease of CO intensity of GDP in 2020 and its influences on achieving National Determined Contribution (NDC) target in 2030 with scenario analysis. The results show that China’s CO intensity of GDP in 2020 is expected to fall by 52.9%–54.4% than the 2005 level, and will be 22.9%–25.4% lower than 2015. Therefore, it is likely to overfulfill the decrease of CO intensity of GDP by 18% proposed in the 13th FYP period. Furthermore, the emission reduction potentiality before 2020 will be conducive to the earlier realization of NDC objectives in 2030. China’s CO intensity of GDP in 2030 will fall by over 70% than that in 2005, and CO emissions peak will appear before 2030 as early as possible. To accelerate the transition to a low-carbon economy, China needs to make better use of the carbon market, and guide the whole society with carbon price to reduce emissions effectively. At the same time, China should also study the synergy of policy package so as to achieve the target of emission reduction.

关键词： China’s National Determined Contribution     emission reduction potential     scenario analysis     CO2 emissions peak    

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Impacts of CO2 and H2S on the risk of hydrate formation during pipeline transport of natural gas

Solomon A. Aromada, Bjørn Kvamme

《化学科学与工程前沿（英文）》 2019年 第13卷 第3期   页码 616-627 doi: 10.1007/s11705-019-1795-2

摘要： Evaluation of maximum content of water in natural gas before water condenses out at a given temperature and pressure is the initial step in hydrate risk analysis during pipeline transport of natural gas. The impacts of CO and H S in natural gas on the maximum mole-fractions of water that can be tolerated during pipeline transport without the risk of hydrate nucleation has been studied using our novel thermodynamic scheme. Troll gas from the North Sea is used as a reference case, it contains very negligible amount of CO and no H S. Varying mole-fractions of CO and H S were introduced into the Troll gas, and the effects these inorganic impurities on the water tolerance of the system were evaluated. It is observed that CO does not cause any distinguishable impact on water tolerance of the system, but H S does. Water tolerance decreases with increase in concentration of H S. The impact of ethane on the system was also investigated. The maximum mole-fraction of water permitted in the gas to ensure prevention of hydrate formation also decreases with increase in the concentration of C H like H S. H S has the most impact, it tolerates the least amount of water among the components studied.

关键词： hydrate     hydrogen Sulphide     CO2     dew point     pipeline    

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Inexpensive synthesis of a high-performance Fe

Imran, Muhammad S. Haider, Hee Taik Kim

《化学科学与工程前沿（英文）》 2016年 第10卷 第3期   页码 405-416 doi: 10.1007/s11705-016-1579-x

摘要： A sol-gel technique has been developed for the synthesis of a magnetite-silica-titania (Fe O -SiO -TiO ) tertiary nanocomposite with improved photocatalytic properties based on the use of inexpensive titania and silica precursors. The exceptional photocatalytic activity of the resulting materials was demonstrated by using them to photocatalyze the degradation of methylene blue solution. The best formulation achieved 98% methylene blue degradation. An interesting feature of the present work was the ability to magnetically separate and reuse the catalyst. The efficiency of the catalyst remained high during two reuses. The synthesized nanomaterials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, ultra-violet-visible spectroscopy, diffuse reflectance spectroscopy, and thermogravimetric analysis. XRD analysis revealed the formation of multicrystalline systems of cubic magnetite and anatase titania crystals. SEM and TEM characterization revealed well-developed and homogeneously dispersed particles of size less than 15 nm. FTIR spectra confirmed the chemical interaction of titania and silica. It was further noticed that the optical properties of the prepared materials were dependent on the relative contents of their constituent metal oxides.

关键词： sol-gel     photocatalysis     magnetic recovery     TiO2     Fe3O4     SiO2    

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CO<sub>2sub> capture using membrane contactors: a systematic literature review

Sanaa Hafeez, Tayeba Safdar, Elena Pallari, George Manos, Elsa Aristodemou, Zhien Zhang, S. M.

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 720-754 doi: 10.1007/s11705-020-1992-z

摘要： With fossil fuel being the major source of energy, CO emission levels need to be reduced to a minimal amount namely from anthropogenic sources. Energy consumption is expected to rise by 48% in the next 30 years, and global warming is becoming an alarming issue which needs to be addressed on a thorough technical basis. Nonetheless, exploring CO capture using membrane contactor technology has shown great potential to be applied and utilised by industry to deal with post- and pre-combustion of CO . A systematic review of the literature has been conducted to analyse and assess CO removal using membrane contactors for capturing techniques in industrial processes. The review began with a total of 2650 papers, which were obtained from three major databases, and then were excluded down to a final number of 525 papers following a defined set of criteria. The results showed that the use of hollow fibre membranes have demonstrated popularity, as well as the use of amine solvents for CO removal. This current systematic review in CO removal and capture is an important milestone in the synthesis of up to date research with the potential to serve as a benchmark databank for further research in similar areas of work. This study provides the first systematic enquiry in the evidence to research further sustainable methods to capture and separate CO .

关键词： CO2 capture     preferred reporting items for systematic reviews and meta-analyses     membrane contactor     absorbent    

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Performance and mechanism of carbamazepine removal by FeS-SO process: experimental investigation and DFT calculations

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1713-1

摘要：

● Synergistic removal of carbamazepine (CBZ) was obtained in the FeS-S2O82– process.

关键词： FeS     S2O82–     Carbamazepine     DFT calculations     Degradation routes    

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Uncovering CO<sub>2sub> emission drivers under regional industrial transfer in China’s Yangtze River

Huijuan JIANG, Yong GENG, Xu TIAN, Xi ZHANG, Wei CHEN, Ziyan GAO

《能源前沿（英文）》 2021年 第15卷 第2期   页码 292-307 doi: 10.1007/s11708-020-0706-z

摘要： With the relocation of heavy industries moving from downstream region to upstream and midstream regions in the Yangtze River Economic Belt (YREB), it is critical to encourage coordinated low carbon development in different regions within the YREB. This paper uncovers the evolution of CO emissions in different regions within the YREB for the period of 2000–2017. It decomposes regional CO emission changes using the temporal and cross-regional three-layer logarithmic mean Divisia index (LMDI) method. Besides, it decomposes industrial CO emission changes using the temporal two-layer LMDI method. The research results show that economic growth is the major driver for regional CO emission disparities. The mitigation drivers, such as energy intensity and energy structure, lead to a more decreased CO emission in the downstream region than in the upstream and midstream regions. In addition, it proposes several policy recommendations based upon the local realities, including improving energy efficiency, optimizing energy structure, promoting advanced technologies and equipment transfers, and coordinating the development in the upstream, midstream and downstream regions within the YREB.

关键词： CO2 emission     multi-layer LMDI decomposition     industrial transfer     governance    

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China’s carbon neutrality: an extensive and profound systemic reform

《环境科学与工程前沿（英文）》 2023年 第17卷 第2期 doi: 10.1007/s11783-023-1614-3

摘要：

● China has pledged ambitious carbon peak and neutrality goals for mitigating global climate change.

关键词： Carbon neutrality     Energy structure     Technology-dependent society     Coordinated mitigation for air pollutants and CO2    

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Highly effective visible-photocatalytic hydrogen evolution and simultaneous organic pollutant degradation over an urchin-like oxygen-doped MoS/ZnInS composite

《环境科学与工程前沿（英文）》 2022年 第16卷 第10期 doi: 10.1007/s11783-022-1566-z

摘要：

● An urchin-like OMS/ZIS composite was fabricated by a facile solvothermal method.

关键词： Dual-functional photocatalysts     Oxygen-doped MoS2/ZnIn2S4     H2 evolution     Organic pollutant    

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VALORIZATION OF BIOGAS THROUGH SIMULTANEOUS CO AND HS REMOVAL BY RENEWABLE AQUEOUS AMMONIA SOLUTION IN MEMBRANE CONTACTOR

《农业科学与工程前沿（英文）》 2023年 第10卷 第3期   页码 468-478 doi: 10.15302/J-FASE-2022473

摘要：

● Simultaneous H2S and CO2 removal from biogas is studied.

关键词： biomethane     biogas purification     CO2 removal     H2S removal     membrane absorption    

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Orderly decorated nanostructural photoelectrodes with uniform spherical TiO

Bakhshayesh,S. S. Azadfar

《化学科学与工程前沿（英文）》 2015年 第9卷 第4期   页码 532-540 doi: 10.1007/s11705-015-1549-8

摘要： This study presents a novel nanostructural electrode made of 20-nm-diameter nanoparticles, which orderly decorated with 2-µm TiO particles, deposited by a new gel process. The decorated electrode (DE) is better than the non-decorated electrode (NE) in both light scattering and light harvesting, as confirmed by diffuse reflectance spectroscopy. X-ray diffraction reveals that both electrodes have a mixture of anatase and rutile phases. The dye-sensitized solar cell based on the decorated electrode shows the highest power conversion efficiency of 7.80% as a result of less recombination demonstrated by electrochemical impedance spectroscopy. From internal power conversion efficiency measurement, the external quantum efficiency of DE cell at 530 nm is 89%, which is higher than that of NE cell (77%).

关键词： dye-sensitized solar cell     uniform particles     TiO2 gel process     light harvesting    

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标题 作者 时间 类型 操作

In-MOF-derived In<sub>2sub>S<sub>3sub>/Bi<sub>2sub>S<sub>3sub> heterojunction for enhanced photocatalytic

期刊论文

NO<sub>xsub> and H<sub>2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

期刊论文

Photoelectrocatalytic generation of H and S from toxic HS by using a novel BiOI/WO nanoflake array photoanode

期刊论文

催化氧化净化黄磷尾气中的磷和硫

宁平,Hans-JörgBart,王学谦,马丽萍,陈梁

期刊论文

Sulfur-deficient CoNi<sub>2sub>S<sub>4sub> nanoparticles-anchored porous carbon nanofibers as bifunctional

期刊论文

China’s pre-2020 CO

Hailin WANG

期刊论文

Impacts of CO2 and H2S on the risk of hydrate formation during pipeline transport of natural gas

Solomon A. Aromada, Bjørn Kvamme

期刊论文

Inexpensive synthesis of a high-performance Fe

Imran, Muhammad S. Haider, Hee Taik Kim

期刊论文

CO<sub>2sub> capture using membrane contactors: a systematic literature review

Sanaa Hafeez, Tayeba Safdar, Elena Pallari, George Manos, Elsa Aristodemou, Zhien Zhang, S. M.

期刊论文

Performance and mechanism of carbamazepine removal by FeS-SO process: experimental investigation and DFT calculations

期刊论文

Uncovering CO<sub>2sub> emission drivers under regional industrial transfer in China’s Yangtze River

Huijuan JIANG, Yong GENG, Xu TIAN, Xi ZHANG, Wei CHEN, Ziyan GAO

期刊论文

China’s carbon neutrality: an extensive and profound systemic reform

期刊论文

Highly effective visible-photocatalytic hydrogen evolution and simultaneous organic pollutant degradation over an urchin-like oxygen-doped MoS/ZnInS composite

期刊论文

VALORIZATION OF BIOGAS THROUGH SIMULTANEOUS CO AND HS REMOVAL BY RENEWABLE AQUEOUS AMMONIA SOLUTION IN MEMBRANE CONTACTOR

期刊论文

Orderly decorated nanostructural photoelectrodes with uniform spherical TiO

Bakhshayesh,S. S. Azadfar

期刊论文